This article is cited in 2 papers

Magnetism

Visualization of the atomic structure of solid solutions with the NaCl structure

Yu. A. Babanov, D. A. Ponomarev, V. V. Ustinov

Institute of Metal Physics, Ural Branch of the Russian Academy of Sciences, Ekaterinburg

Abstract: It has been shown how an atomic cluster for a solid solution with a rock salt structure can be constructed using the Pauling model. Simulation has been performed for 343000 ions of Ni$_x$Zn$_{1-x}$O$_3$ ($x$ = 0, 0.3, 0.5, 0.7, 1.0) oxide substitutional solid solutions. Coordinates of all cluster ions are obtained and distribution functions of ion pairs (Ni–O, Ni–Ni, Ni–Zn, Zn–Zn, Zn–O, O–O) are constructed as functions of distance. The shape of the normal distribution indicates the existence of bounded chaos in the system of oxide solid solutions. The width of the Gaussian distribution function is determined by the difference of metal ionic radii. The results are in agreement with both X-ray diffraction and EXAFS spectroscopy data.

Received: 23.10.2014

 English version: Physics of the Solid State, 2015, 57:4, 717–721

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