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JOURNALS // Fizika Tverdogo Tela // Archive

Fizika Tverdogo Tela, 2024 Volume 66, Issue 4, Pages 579–584 (Mi ftt10282)

Ferroelectricity

Dielectric and optical properties of transparent ceramics K$_{0.5}$Na$_{0.5}$NbO$_3$–0.02 Ba$_2$NaNb$_5$O$_{15}$

L. S. Kamzina

Ioffe Institute, St. Petersburg, Russia

Abstract: The relationship between depolarization temperature $T_d$ and polymorphic phase transition temperature $T_{\mathrm{F-R}}$ in poorly studied relaxor hot-pressed ceramics (K$_{0.5}$Na$_{0.5}$) $\cdot$ NbO$_3$–0.02 Ba$_2$NaNb$_5$O$_{15}$ was studied. Dielectric and optical properties of polarized samples were measured for this purpose. It was found that the temperatures $T_d$ and $T_{\mathrm{F-R}}$ do not match. The obtained results are discussed in terms of the degree of the phase transition diffuseness and the size of the polar regions. It is suggested that the relative position of the depolarization temperature and the temperature of transition of the polarized sample to the relaxor phase $T_{\mathrm{F-R}}$ does not depend on the type of phase boundary (polymorphic or morphotropic), but is related only to the size of the polar regions.

Keywords: lead-free transparent ceramics, polymorphic phase transition, relaxors.

Received: 28.02.2024
Revised: 28.02.2024
Accepted: 27.03.2024

DOI: 10.61011/FTT.2024.04.57794.39



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© Steklov Math. Inst. of RAS, 2026