This article is cited in 1 paper

Thermodynamic study of synthesis of titanium boride by the method of condensation combustion of gases

Yu. M. Burov, Yu. M. Grigor'ev, S. G. Kuzminskaya

Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow region

Abstract: We have performed a thermodynamic calculation of the adiabatic combustion temperatures and equilibrium composition of products in the BCl$_3$ – TiCl$_4$ – Na system at atmospheric pressure and temperatures of 300–3000 K. The maximum combustion temperature is equal to 1872 K. The conditions under which the final high-melting products Ti, TiB, TiB$_2$, and B are produced have been found. The results obtained enable one to choose the conditions for synthesis of highly disperse powders of high-melting compounds and coatings based on them using combustion processes.

UDC: 539.236+621.3.038

Received: 19.06.1996
Accepted: 30.10.1996

 English version: Combustion, Explosion and Shock Waves, 1997, 33:5, 548–552