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Fizika Goreniya i Vzryva, 2007 Volume 43, Issue 6, Pages 13–20 (Mi fgv1541)

Method of estimating absolute concentrations of Ñ$_2$H$_5$ and H radicals in hydrocarbon diffusion flames

G. A. Makhov

Institute of Chemical Kinetics and Combustion, Siberian Division, Russian Academy of Sciences, Novosibirsk, 630090

Abstract: A method for estimating absolute concentrations of Ñ$_2$H$_5$ and H radicals in hydrocarbon diffusion flames is proposed and substantiated. Concentration profiles of Ñ$_2$H$_5$ and H on the flame axis are obtained. In the method proposed, the concentration of Ñ$_2$H$_5$ is determined from the equality of two quantities – the rate of loss of n-butane by diffusion and the rate of its formation by recombination of two Ñ$_2$H$_5$ radicals. The concentration of H radicals is determined from the relation between the ratio Ñ$_2$H$_5$/H and experimental profiles of Ñ$_2$H$_4$, Ñ$_2$H$_6$, and O$_2$.

Keywords: absolute concentration of radicals, Ñ$_2$H$_5$, H, laminar diffusion flame, propane, diffusion.

UDC: 536.46

Received: 03.08.2006
Accepted: 05.12.2006


 English version:
Combustion, Explosion and Shock Waves, 2007, 43:6, 628–635

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